Ok here's the super short answer on clip-ons and alignment with the day optic.
Will misalignment work? As Wigwamitus says it will work. BUT... and there is always a BUT, you are cheating your self out of the critical performance that you just paid a huge amount of cash for. NOW, that being said, The CNVD-LR and the PVS-24 to a lesser degree are WAY more sensitive to this misalignment because their Risley Prisms are further away from the tubes output screen than any other clip on design. The FLIR stuff, as well as the Knights offering, operate on a different design placement of their corrective methods, so they are more tolerant of misalignment.
It is ALWAYS best to align the clip on with the day optic for both angle and height. If you do this you're getting the optimum performance out of your MANY thousand dollar optic. What do I mean by optimum performance? Really clear picture and better light transmission! The image intensifiers BEST resolution is in the center. The only exception to this is the new White Phosphor Photonis 4G Knights PVS-30s. They have a different tube than a regular 11769 found in a regular PVS 14 that corrects for edge to edge resolution drop off better than every other image intensifier. Soooo by not... aligning the optics, let me give you an analogy? It is like buying a Ferrari and then running incorrectly rated tires and low octane gas. WHY do that?
In closing let me say, LINE UP your clip-ons up with your day optics. Do whatever you have to do in your rails/chassis systems to accomplish this. If you do, you will get noticeably better image quality!
I2 Tech