If it makes you happy, enjoy y'erself.
If you expect sorting by weight or different cartridge dimensions,
to improve results on target, you likely are an optimist.
Which portion of the rim do you measure?
The part where the firing pin impacts, correct?
Do you think the rim is the same thickness the entire circumference?
Might want to verify that.
Do you think the brass thickness that forms the rim
is the same on every cartridge? How about brass hardness?
Will measuring the rim affect powder or primer chemistry or amounts?
Will the rim dimension affect bullet weight/shape?
How will the rim relate to assembly variations?
How many cartridges will be needed to be measured,
to prevent normal variations in cartridge quality
from skewing the conclusion?
These are all questions that bother me when sorting by any methods.