Jesus Ryan, quit talking in veiled bullshit.
Jacketed match bullets can start seeing integrity issues as low as 325,000 rpm.
You SOUND like you're talking about 5.56--an area I have quite some experience with--and equating it to Valkyrie. Not the same thing at all, but you refuse to clarify or cite.
At the speeds a longer Valkyrie is likely going to generate with hand loaded casings, that extra half inch tighter twist may make a really big goddamn difference.
My LR and Palma barrel is an 8-6.6 progressive, and it's great. I NEED that twist rate because I FILL a couple of those boxes I listed up there: short barrel + only 90s. It's also only a .223.
So no, the chart has nothing to do with cartridge specificity per se, but the way it is USED can certainly help with cartridge selection, barrels, bullets...
It's not perfect and it isn't gospel, for one because some bullets are tough and some barrels are polygonal, but it's a far sight better than 'because I think so, and the Army said it works in 5.56'.