Re: Sig 5.56 chamber end of the barrel question...
1st question is what kind of mags are you using? If they're Sig factory mags, place them gently in an appropriate cylindrical receptacle, then get yourself some P-Mags and see if the feeding issues don't disappear. I have several Sig 556s, none of which has had any feeding problems [that could be attributed to the ammo] using many different types of factory ammo. However, I have seen many FTFs due to the Sig factory mags. This was particularly noticeable using longer rounds, such as 75 gr and 77 gr match BTHPs, which I believe is caused by the bullet meplat dragging against the inside wall of the Sig mags (they are quite short internally [lengthwise] as compared to P-Mags). The flat meplat of the longer BTHP match rounds seems to get hung up on the inside wall of the mag. This type of problem did not occur using Sig mags with non-HP or plastic-tipped HP loads of similar length, I'm guessing because the shape of the tip was less of a problem for proper feeding even though these rounds also actually would touch the inside wall of the mag. These issues disappeared after I switched to P-Mags.
Alternatively, you didn't state exactly which Prvi match ammo you were using (69 gr?, 75 gr?), but have you tried a similar load from a different manufacturer to see whether they behave similarly? You may be right about the shape of the chamber area, although it doesn't seem as though that is the most likely thing to check first. Also, have you talked to Sig about this issue? In any case, good luck with it!