bruddah,
You and I are on about the same page at this point. The 77gr. SMK over 5.56MM pressure TAC shoots fine at around 0.5 MOA in good conditions; I have been using it since around 2006. But TAC is pretty much a typical double based powder in that it is thermally sensitive, looks like to the tune of 0.8 FPS/1 degree F from -10F to +135F in the 18" barrel I now use. Several shooters in our group, including myself, used the 77gr. SMK over 5.56MM pressure Varget for years prior to using TAC and accuracy with almost absolute thermal stability were there with Varget. But when the factory MK 262 MOD 1 cartridge became widely available, we found it was almost 150FPS faster than our Varget load due to the non-canister spherical double based propellant used. Most of us were using 24" or even 26" barrels at that time so low MV was not an issue using Varget. But when using an 18" barrel, the Varget loads were getting a bit on the puny side. We then worked up a 5.56MM pressure TAC loading modeled after the factory BHA MK 262 loading which shot quite well. Another propellant that several people above have mentioned & is worth testing with is H4895. It is almost as thermally stable as Varget but has the potential to get MV up to within 85 FPS of the MK 262 cartridge which is a very accurate MV in this 18" barrel. Although I have not had a chance to do a full work up using 8208 yet, it is top of my dance card for after the hunting season ends. Initial tests with 8208 indicate it may give up just a very slight amount of thermal stability as compared to Varget or H4895 but MV is just as high as with H4895 with better ES/SD numbers to help control vertical stringing at medium to LR. The bad news is you are pretty much on your own with 5.56 pressure loadings of 8208 as very little 5.56MM loading data is out there yet. My choice between H4895 or 8208 in 77gr. SMK & over-mag-length 80gr. VLD accuracy loads for this 18" barrel will be based on the actual MV/ES/SD/accuracy seen. Thermal stability should not be an issue with H4895, Varget, or 8208 so your thinking is sound IMO. .02