I will have to take a closer look tonight, but yes, I think the nose of the bullet is missing the entrance to the chamber and jamming against the breech face of the barrel. I did slightly modify this MDT mag to work in another 223 bolt gun, and what I did was remove a little bit of the front of the feed lips to allow the cartridge to "angle up" a little more as it is pushed from the mag so this could be contributing to the issue?
I guess I would have to order another MDT mag to see if an unmodified one will still have the same issue. Still seems strange that I am unable to just single load them on top of the magazine tho.
When you get a chance to look at it see if the bullet is missing the chamber high or missing low. If it's missing high then the feedlips might be a contributing factor. The next thing to look at is height of magazine relative to action. If the mag is low its more likely to send the round high, if the mag is high then it's more likely to send the round lower. At least that's what my guess is... seems like a low mag would have the round hit off the feed ramp and angle the bullet more sharply upwards. Try feeding a round super slow and watching what it does.